Asphalt-Rubber Sets the Bar for Modified Binders

By Donna J. Carlson, Director of Communications Editor RPA News

Asphalt-Rubber, which has been around since the 1960's, was first defined in 1988 by ASTM, a universally recognized technical body, as "A blend of asphalt cement, reclaimed tire rubber, and certain additives in which the rubber component is at least 15%* by weight of the total blend and has reacted in the hot asphalt sufficiently to cause swelling of the rubber particles."

* Standard practice in user agencies is 18-20% percent rubber.

    Asphalt-Rubber was first introduced in Arizona as a patented process, with different patents being held by two entities. One by inventor Charles McDonald, who licensed Altos Rubber which then issued a sublicense to Sahuaro Petroleum Company. Later Arizona Refining Company, a subsidiary of Unocal, developed a parallel process based on similar high percentages of rubber but with different types of material (high natural rubber) and asphalts.
   The first applications, after the initial "band aid" pothole patches used on streets by McDonald, the Engineering Supervisor for the City of Phoenix, were spray applied "Chip Seals." The chip seals, with the highly vicious rubber and asphalt binder, necessitated the development of equipment specially designed to handle the material. The company developing the first equipment was Bearcat of Wickenburg, Arizona. Today there are several companies offering Asphalt-Rubber distributors and blenders. Among them, CEI Enterprises of Albuquerque, New Mexico, Hot Mix Industries of Texas and Valley Slurry Seal (VSS) Macropaver Division of Hickman, California. However, many contracting companies build their own equipment.
    The Arizona DOT became involved with the material in the mid sixties, working with McDonald and the City of Phoenix. Gene Morris, P.E. the ADOT Asst. District Engineer for the Phoenix district at that time began to try different applications of the materials. Morris was later named Research Engineer and despite the usual early "disasters," pressed ADOT forward with research and test sections. Their work through the years has led to successful routine usage of the process in seal coats, interlayer, membranes, gap-graded Asphalt-Rubber concrete and open-graded Asphalt-Rubber concrete surface courses. Today, the Arizona DOT has over 3,500 miles of its 7,000-mile state highway and interstate system paved with Asphalt-Rubber.
    Interest in the new process material intrigued highway materials researchers and led to the First Seminar on Asphalt-Rubber in Scottsdale, Arizona in 1980. The meeting was sponsored by the FHWA, the Arizona Department of Transportation; Genstar Conservation Systems, Inc.; Arizona Refining Company, Sahuaro Petroleum and Engineers Testing Laboratory. The FHWA had commissioned a demonstration project in 1976 in which 43 Asphalt-Rubber demonstration projects were constructed in various states. The FHWA program included 16 chip seals, 23 interlayers, 3 bridge deck seals and 1 embankment stabilization.
    At the seminar, a $3,500,000 research, development and implementation needs program was developed to build on the seven technical presentations and the 66 major research papers referenced at the conference. Even at that date, the research was not limited to the U.S., fourteen reports came from Canada, two from Australia, one from Great Britain and one from France. Today, over one thousand major reports chronicle the development and success of Asphalt-Rubber.

    John Epps, Ph.D, P.E., and Bob Galloway both of Texas A&M University wrote the conference summary. The conclusions of the summary contained some positive statements:

  • 1. "Asphalt-Rubber is a viable material that provides an attractive economic alternative for construction, rehabilitation and maintenance of our nation's roadway network. Economic advantages stem from increased life and reduced thicknesses of pavement section. In addition the material is attractive from an energy and resource recovery
    point of view."
  • 2. "Asphalt-Rubber is a new binder system and does not respond to analysis by conventional tests associated with asphalt technology. Furthermore, the binder and the binder-aggregate system are both chemically and mechanically complex and far from being fully understood."
  • 3. "A nationally recognized group of users, producers and researchers needs to help formulate research and development programs, monitor research, sponsor conferences, workshops, etc. It is recommended that the Transportation Research Board create a Task Force on Asphalt-Rubber Binder Systems and that ASTM Subcommittee on D04.37 actively pursue the standardization of test methods, quality control techniques and definitions. User-producer workshops should be continued to provide an open forum for discussion of the problems associated with the new and emerging binder systems."

 

  • 4. "Additional research, development and implementation efforts need to be undertaken to improve the economy and predictability of performance of the asphalt-rubber binder for specific applications. These efforts have been identified in this conference and appear in the proceedings."

 

   Time and perseverance by agencies like ADOT, TXDOT, the FHWA, Caltransmnand the Rubber Pavements Association has fulfilled the expectation of the seventy-eight attendees of the 1980 Asphalt-Rubber User-Producer workshop. The agencies have moved forward with research in the field and their labs; RPA provides seminars and workshops on an international basis and has commissioned much of the research identified 23 years ago. ASTM has adopted a definition and standards and research is continuing at well-known Universities throughout the US and in other countries. Four of the attendees of this historic conference now serve on the 19 member RPA Technical Advisory Board; Doug Bernard, P.E. FHWA ret., Dr. Jon Epps, Prof. Emeritus University of Nevada Reno, Dr. Rudy Jimenez, Prof. Emeritus, University of Arizona and Gene Morris, P.E., ADOT ret.
    In the early years of the material, no one really thought much about the tire recycling aspect, as the discarded tire problem was not fully recognized by the nation until the late 80s and early 90s. Even today, most highway engineers will tell you that performance of the material outweighs its recycling benefits in their decision process. However, once
the appeal and success of the environmentally enhanced asphalt material started spreading beyond the three original states, it also caught the attention of the oil companies as a means of making healthy profits on modified asphalt binders. It appears the oil companies decided they wanted a bigger piece of the market share than being an asphalt supplier afforded them. Soon a proliferation of modified binders hit the market, with their owners claiming they too contained recycled scrap tire rubber. The problem is that the majority, if not all the new "rubberized" asphalt binders are blended at the oil terminals, and have specifications that require a very fine gradation of rubber. The rubber content of these materials range from a low of 3 or 4% to a high of 10%. Verification on the actually rubber content relies on a "certification" as opposed to the visual "inspection" process available with the Asphalt-Rubber materials. Some products require proof of the absence of the rubber via solubility tests.
    According to Gene Morris, the low percentage of fine grind rubber was tested and rejected by ADOT as failing to achieve an equivalent level of properties and field performance as the mixtures containing the higher percentage of coarser rubber particles. Morris has postulated that a minimum percentage and size of the swollen rubber particles is necessary to form a continuous elastomeric phase in the reacted material. This continuous phase is necessary to prevent reflective cracking, provide the significant increase in resistance to aging, and to develop the modifications in behavior that result in material improvements in both the high and low temperature ranges of pavement performance. Also these properties developed with the ASTM defined Asphalt-Rubber permit a significant increase in the binder content of asphalt concrete plant mixes. This increase substantially improves the pavement performance with respect to resistance to cracking, aging, pavement life and maintenance costs. A real world example of the performance improvement was demonstrated in the first thin overlay of a Portland Cement Concrete pavement. In 1988 the I-19 south of Tucson, Az, was overlaid with a 1" thick open-graded Asphalt-Rubber mixture. In 2001 an in-depth inspection of this 2-mile section revealed no reflective cracking, high skid resistance, and zero surface maintenance costs over the 13-year period of use. (The I-19 is the major produce-trucking route from Nogales, Mexico to the U.S.)
    According to Morris, Vice Chairman of the Technical Advisory Board for RPA, resistance to reflective cracking is thought to be a function of the elastic deformation of the binder, particularly in the post failure zone, and the reduction of the coefficient of thermal expansion. Morris claims neither of these improvements can be obtained with low percentages of fine grind rubber. He is adamant in his claims that extensive research, field evaluations and long-term performance have shown that a minimum of 15 percent of ground rubber, properly reacted with asphalt, is necessary to achieve this type of performance. When one examines the countless research performed by leaders in the field of asphalt technology, it would be difficult to dispute Morris's claims. In commenting on the "new generation" of terminal blended modified binders who claim to be "equivalent" to Asphalt-Rubber, Morris challenges the producers to reveal the research and long-term performance to support their claims.
    The claims, as stated in their advertising, often defy logic and engineering principles, such as more binder produces a better performing mix. A good example is an ad, which appears in a west coast industry magazine. In the ad the benefits of the material are touted in four bullet points. Three of the points are reasonable but the one that catches the eyes of an "old asphalt hand" like Morris is "Cost Savings.Allows for Lower Asphalt Binder Content in Mix." This combined with a misleading statement "A Refinery Produced Asphalt Rubber Binder" should give one an insight to their marketing strategy of aligning their products with the real ASTM defined Asphalt-Rubber that has years of research and proven performance. It is interesting to note that the modified binder proponents are calling for a new definition of Asphalt-Rubber, presumably with something less than a minimum 15% rubber content to legitimize their misuse of the term Asphalt-Rubber.
    Is their strategy working? Unfortunately, in some cases it is. The RubberPavements Association, often gets calls from agencies complaining that they tried Asphalt-Rubber and it failed. When asked about the rubber content of the mix, they are sometimes shocked to learn they did not use Asphalt-Rubber at all, but had placed a terminal blended product thatnot only contained less than 15%, in most cases, less than 10% rubber.

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